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Lecture 3.2 — Entanglement and the Bell States

Purdue University

Where We Left Off

Last lecture we built the machinery for two-qubit states: the tensor product \otimes, the amplitude table CijC_{ij}, and the 6=4+26 = 4 + 2 DOF counting that told us correlations must exist.

Today we make that concrete. We’ll learn to test whether a state is entangled, meet the four Bell states — the maximally entangled two-qubit states that form the backbone of quantum information — and review the measurement formalism we’ll need to analyze them.


Part 1: Review and Practice

The General Two-Qubit State

The most general state of two qubits is:

Ψ=C0000+C0101+C1010+C1111|\Psi\rangle = C_{00}|00\rangle + C_{01}|01\rangle + C_{10}|10\rangle + C_{11}|11\rangle

Four complex amplitudes, satisfying Cij2=1\sum|C_{ij}|^2 = 1.

Independent Qubits: The Tensor Product

If qubit A is in state ψ=a0+b1|\psi\rangle = a|0\rangle + b|1\rangle and qubit B is in state ϕ=c0+d1|\phi\rangle = c|0\rangle + d|1\rangle, and they are independent, the joint state is:

ψϕ=ac00+ad01+bc10+bd11|\psi\rangle \otimes |\phi\rangle = ac|00\rangle + ad|01\rangle + bc|10\rangle + bd|11\rangle

The amplitudes are products: Ψij=uivj\Psi_{ij} = u_i v_j. This is the quantum version of PAB(i,j)=PA(i)PB(j)P_{AB}(i,j) = P_A(i) \cdot P_B(j) — independence means the joint state factors.

The answer is (C). With a=1a = 1, b=1b = -1, c=1c = 1, d=1d = 1:

ac00+ad01+bc10+bd11=00+011011ac|00\rangle + ad|01\rangle + bc|10\rangle + bd|11\rangle = |00\rangle + |01\rangle - |10\rangle - |11\rangle

The pattern makes sense: qubit A contributes a minus sign whenever it’s in state 1|1\rangle, because b=1b = -1.


Part 2: Entanglement

Can Every State Be Factored?

Consider the state:

Φ+=12(00+11)|\Phi^+\rangle = \frac{1}{\sqrt{2}}(|00\rangle + |11\rangle)

Can we write this as ψϕ=(a0+b1)(c0+d1)|\psi\rangle \otimes |\phi\rangle = (a|0\rangle + b|1\rangle) \otimes (c|0\rangle + d|1\rangle)?

Let’s try. Matching coefficients to ac00+ad01+bc10+bd11ac|00\rangle + ad|01\rangle + bc|10\rangle + bd|11\rangle:

ac=12,bd=12ac = \frac{1}{\sqrt{2}}, \qquad bd = \frac{1}{\sqrt{2}}
ad=0,bc=0ad = 0, \qquad bc = 0

From ad=0ad = 0: either a=0a = 0 or d=0d = 0. From bc=0bc = 0: either b=0b = 0 or c=0c = 0.

But if a=0a = 0, then ac=012ac = 0 \neq \frac{1}{\sqrt{2}}. If d=0d = 0, then bd=012bd = 0 \neq \frac{1}{\sqrt{2}}. Same problem with b=0b = 0 or c=0c = 0.

No assignment of a,b,c,da, b, c, d works. This state cannot be written as a tensor product.

This means three things — all equivalent ways of saying the same thing:

  1. The state cannot be written as a tensor product of single-qubit states.

  2. The two qubits are not independent — they are correlated.

  3. The state is entangled.


The Determinant Test

Trying to factor states by hand is tedious. We need a systematic test.

Recall from last lecture that we can arrange the four amplitudes of any two-qubit state into a 2×22 \times 2 amplitude table:

C=(C00C01C10C11)C = \begin{pmatrix} C_{00} & C_{01} \\ C_{10} & C_{11} \end{pmatrix}

For a product state, this matrix is an outer product of two vectors:

C=uvT=(ab)(cd)=(acadbcbd)C = \vec{u}\,\vec{v}^T = \begin{pmatrix} a \\ b \end{pmatrix}\begin{pmatrix} c & d \end{pmatrix} = \begin{pmatrix} ac & ad \\ bc & bd \end{pmatrix}

An outer product of two vectors is a rank-1 matrix — its rows (or columns) are proportional to each other. Rank-1 matrices have a simple property: their determinant is zero.

det(uvT)=(ac)(bd)(ad)(bc)=abcdabcd=0\det(\vec{u}\,\vec{v}^T) = (ac)(bd) - (ad)(bc) = abcd - abcd = 0

This gives us a clean test:

Why does this work? A 2×22 \times 2 matrix can be written as an outer product of two vectors if and only if it has rank 1, which for a 2×22\times 2 matrix is equivalent to having determinant zero. The determinant measures exactly the “entanglement content” — how far the amplitude table is from being factorable.


Practice: Entangled or Not?

Build the amplitude table and compute the determinant:

C=(1111),det(C)=(1)(1)(1)(1)=0C = \begin{pmatrix} 1 & 1 \\ 1 & 1 \end{pmatrix}, \qquad \det(C) = (1)(1) - (1)(1) = 0

Not entangled. We can factor it:

00+01+10+11=(0+1)(0+1)|00\rangle + |01\rangle + |10\rangle + |11\rangle = (|0\rangle + |1\rangle) \otimes (|0\rangle + |1\rangle)

(up to normalization). Both qubits are independently in the +|+\rangle state.


C=(1111),det(C)=(1)(1)(1)(1)=11=0C = \begin{pmatrix} 1 & -1 \\ -1 & 1 \end{pmatrix}, \qquad \det(C) = (1)(1) - (-1)(-1) = 1 - 1 = 0

Not entangled. The factorization is:

000110+11=(01)(01)|00\rangle - |01\rangle - |10\rangle + |11\rangle = (|0\rangle - |1\rangle) \otimes (|0\rangle - |1\rangle)

Both qubits are in the |-\rangle state.


Now try 00+11|00\rangle + |11\rangle:

C=(1001),det(C)=(1)(1)(0)(0)=10C = \begin{pmatrix} 1 & 0 \\ 0 & 1 \end{pmatrix}, \qquad \det(C) = (1)(1) - (0)(0) = 1 \neq 0

Entangled. The amplitude table is the identity matrix — it has rank 2, not rank 1. No choice of single-qubit states can produce it. This is the state we tried (and failed) to factor by hand earlier.


The pattern is becoming clear: states where both diagonal entries are nonzero but the off-diagonal entries are zero (or vice versa) tend to be entangled — the two qubits are “doing different things together” in a way that can’t be separated.


Part 3: The Bell States

We’ve seen that 12(00+11)\frac{1}{\sqrt{2}}(|00\rangle + |11\rangle) is entangled. In fact, it’s one of four special entangled states that form a complete orthonormal basis for the two-qubit Hilbert space.

The Four Bell States

Φ+=00+112Φ=00112|\Phi^+\rangle = \frac{|00\rangle + |11\rangle}{\sqrt{2}} \qquad |\Phi^-\rangle = \frac{|00\rangle - |11\rangle}{\sqrt{2}}
Ψ+=01+102Ψ=01102|\Psi^+\rangle = \frac{|01\rangle + |10\rangle}{\sqrt{2}} \qquad |\Psi^-\rangle = \frac{|01\rangle - |10\rangle}{\sqrt{2}}

The naming convention: Φ\Phi states have same-outcome correlations (00|00\rangle and 11|11\rangle), Ψ\Psi states have opposite-outcome correlations (01|01\rangle and 10|10\rangle). The +/+/- superscript is the relative phase between the two terms.

Ψ|\Psi^-\rangle is called the singlet state — it will play a starring role when we get to Bell’s theorem.

Properties

All four are maximally entangled. You can verify: each has an amplitude table with det(C)=1/2|\det(C)| = 1/2 (the maximum possible for a normalized state).

For example:

Φ+:C=12(1001),det(C)=12|\Phi^+\rangle: \quad C = \frac{1}{\sqrt{2}}\begin{pmatrix} 1 & 0 \\ 0 & 1 \end{pmatrix}, \quad \det(C) = \frac{1}{2}
Ψ:C=12(0110),det(C)=12|\Psi^-\rangle: \quad C = \frac{1}{\sqrt{2}}\begin{pmatrix} 0 & 1 \\ -1 & 0 \end{pmatrix}, \quad \det(C) = -\frac{1}{2}

They form an orthonormal basis. Any two-qubit state can be expanded in the Bell basis instead of the computational basis {00,01,10,11}\{|00\rangle, |01\rangle, |10\rangle, |11\rangle\}. The four Bell states are mutually orthogonal:

Φ+Φ=0,Φ+Ψ+=0,Φ+Ψ=0,etc.\langle\Phi^+|\Phi^-\rangle = 0, \quad \langle\Phi^+|\Psi^+\rangle = 0, \quad \langle\Phi^+|\Psi^-\rangle = 0, \quad \text{etc.}

You can verify the first: Φ+Φ=12(00+11)(0011)=12(11)=0\langle\Phi^+|\Phi^-\rangle = \frac{1}{2}(\langle 00| + \langle 11|)(|00\rangle - |11\rangle) = \frac{1}{2}(1 - 1) = 0.

Two complete bases for the same space:

Computational basisBell basis
00|00\rangleΦ+|\Phi^+\rangle
01|01\rangleΦ|\Phi^-\rangle
10|10\rangleΨ+|\Psi^+\rangle
11|11\rangleΨ|\Psi^-\rangle

The computational basis is made of product states — no correlations. The Bell basis is made entirely of maximally entangled states. Both are perfectly valid bases for the 4-dimensional two-qubit Hilbert space.


Part 4: Measurement Formalism

Before we can analyze what happens when you measure entangled states, we need to sharpen our tools. Let’s review the measurement formalism, first for a single qubit.

A Note on Labels and Eigenvalues

The computational basis labels 0|0\rangle and 1|1\rangle are names, not eigenvalues. The Pauli ZZ operator has eigenvalues +1 and -1:

Z0=+0,Z1=1Z|0\rangle = +|0\rangle, \qquad Z|1\rangle = -|1\rangle

So 0|0\rangle means “spin up” (eigenvalue +1) and 1|1\rangle means “spin down” (eigenvalue -1). The X and Y eigenstates follow the same convention:

X+=++,X=Y+i=++i,Yi=iX|+\rangle = +|+\rangle, \quad X|-\rangle = -|-\rangle \qquad Y|{+i}\rangle = +|{+i}\rangle, \quad Y|{-i}\rangle = -|{-i}\rangle

Throughout this course, measurement outcomes are always ±1\pm 1, and basis states are labeled by their eigenvalue sign. When we get to Bell’s theorem, Alice measuring Z and getting 0|0\rangle will correspond to outcome A=+1A = +1.


Projective Measurement: Single Qubit

Suppose we have a qubit in state Ψ=α0+β1|\Psi\rangle = \alpha|0\rangle + \beta|1\rangle and we measure in the Z-basis.

Step 1: Build the projector. For the outcome 0|0\rangle (eigenvalue +1), the projector is 00|0\rangle\langle 0|. As a matrix:

00=(10)(10)=(1000)|0\rangle\langle 0| = \begin{pmatrix} 1 \\ 0 \end{pmatrix}\begin{pmatrix} 1 & 0 \end{pmatrix} = \begin{pmatrix} 1 & 0 \\ 0 & 0 \end{pmatrix}

Step 2: Apply the projector. The (unnormalized) post-measurement state is:

00Ψ=00(α0+β1)=α0|0\rangle\langle 0|\Psi\rangle = |0\rangle\langle 0|(\alpha|0\rangle + \beta|1\rangle) = \alpha|0\rangle

The projector “kills” the 1|1\rangle component and keeps the 0|0\rangle component.

Step 3: Find the probability. The probability of this outcome is the squared norm of the projected state:

p(+1)=Ψ00Ψ=α2p(+1) = \langle\Psi|0\rangle\langle 0|\Psi\rangle = |\alpha|^2

This is just Born’s rule: the probability equals the squared magnitude of the amplitude for that outcome. (We used the projector properties (00)=00(|0\rangle\langle 0|)^\dagger = |0\rangle\langle 0| and (00)2=00(|0\rangle\langle 0|)^2 = |0\rangle\langle 0|.)

Step 4: Normalize. The state after measurement is:

Ψafter=00Ψp(+1)=α0α=eiϕ0|\Psi_{\text{after}}\rangle = \frac{|0\rangle\langle 0|\Psi\rangle}{\sqrt{p(+1)}} = \frac{\alpha|0\rangle}{|\alpha|} = e^{i\phi}|0\rangle

After measuring and getting 0|0\rangle, the qubit is in state 0|0\rangle (up to global phase). The superposition has collapsed.


Measuring in a Different Basis

Now measure the same qubit in the X-basis instead. The eigenstates of XX are:

+=12(0+1),=12(01)|+\rangle = \frac{1}{\sqrt{2}}(|0\rangle + |1\rangle), \qquad |-\rangle = \frac{1}{\sqrt{2}}(|0\rangle - |1\rangle)

The projector onto +|+\rangle is:

++=12(0+1)(0+1)=12(1111)|+\rangle\langle+| = \frac{1}{2}(|0\rangle + |1\rangle)(\langle 0| + \langle 1|) = \frac{1}{2}\begin{pmatrix} 1 & 1 \\ 1 & 1 \end{pmatrix}

Example: Suppose our qubit is already in +=12(0+1)|+\rangle = \frac{1}{\sqrt{2}}(|0\rangle + |1\rangle). What happens when we measure X?

+++=+++1=+|+\rangle\langle+|\,|+\rangle = |+\rangle\underbrace{\langle+|+\rangle}_{1} = |+\rangle

Probability: ++2=1|\langle+|+\rangle|^2 = 1. The measurement gives +|+\rangle (eigenvalue +1) with certainty, and the state is unchanged. This makes sense: +|+\rangle is an eigenstate of X, so measuring X reveals its eigenvalue without disturbing it.

Contrast with Z-measurement: If we instead measured Z on the same state +|+\rangle:

p(+1)=0+2=12,p(1)=1+2=12p(+1) = |\langle 0|+\rangle|^2 = \frac{1}{2}, \qquad p(-1) = |\langle 1|+\rangle|^2 = \frac{1}{2}

Now the outcome is random — 50/50. Measuring in a compatible basis (X) gives a definite result; measuring in an incompatible basis (Z) gives a random one. The state +|+\rangle has a definite X-value but no definite Z-value.

This isn’t an accident — it’s enforced by the mathematics. Let’s see why.


Why Incompatible Bases Give Random Outcomes

Why does 0|0\rangle (definite Z) give completely random results when measured in X? Let’s see it two ways.

The quick way: expand in the other basis. Write 0|0\rangle in the X-eigenbasis:

0=12(++)|0\rangle = \frac{1}{\sqrt{2}}\big(|+\rangle + |-\rangle\big)

It’s an equal-weight superposition of +|+\rangle and |-\rangle. So a measurement of X gives +1 or -1 with equal probability 1/21/2. The outcome is maximally uncertain — as random as a coin flip.

The same holds for Y. In the Y-eigenbasis:

0=12(+i+i)|0\rangle = \frac{1}{\sqrt{2}}\big(|{+i}\rangle + |{-i}\rangle\big)

(up to a relative phase that doesn’t affect probabilities). Again, 50/50.

The systematic way: use σi2=I\sigma_i^2 = I. For any Pauli matrix, σi2=I\sigma_i^2 = I, so σi2=1\langle\sigma_i^2\rangle = 1 in any state. The variance is:

(Δσi)2=σi2σi2=1σi2(\Delta\sigma_i)^2 = \langle\sigma_i^2\rangle - \langle\sigma_i\rangle^2 = 1 - \langle\sigma_i\rangle^2

Maximum uncertainty is Δσi=1\Delta\sigma_i = 1, which happens when σi=0\langle\sigma_i\rangle = 0 — outcomes equally likely, completely random. In a Z-eigenstate:

σx=0σx0=0,σy=0σy0=0\langle\sigma_x\rangle = \langle 0|\sigma_x|0\rangle = 0, \qquad \langle\sigma_y\rangle = \langle 0|\sigma_y|0\rangle = 0
Δσx=Δσy=1(maximal)\Longrightarrow \quad \Delta\sigma_x = \Delta\sigma_y = 1 \quad \text{(maximal)}

Both orthogonal components are individually maximally uncertain. And the same argument holds cyclically: an eigenstate of X is maximally uncertain in Y and Z, and so on.


The Uncertainty Principle

The deeper reason is structural. The spin operators satisfy the commutation relations:

[Sx,Sy]=iSz,[Sy,Sz]=iSx,[Sz,Sx]=iSy[S_x, S_y] = i\hbar S_z, \qquad [S_y, S_z] = i\hbar S_x, \qquad [S_z, S_x] = i\hbar S_y

where Si=2σiS_i = \frac{\hbar}{2}\sigma_i. (In terms of the dimensionless Pauli matrices: [σx,σy]=2iσz[\sigma_x, \sigma_y] = 2i\sigma_z, etc.)

The generalized uncertainty relation says that for any two observables AA and BB:

ΔAΔB12[A,B]\boxed{\Delta A \cdot \Delta B \geq \frac{1}{2}\big|\langle [A, B] \rangle\big|}

where ΔA=A2A2\Delta A = \sqrt{\langle A^2 \rangle - \langle A \rangle^2} is the standard deviation.

Applied to spin in state 0|0\rangle (an eigenstate of SzS_z with Sz=+/2\langle S_z\rangle = +\hbar/2):

ΔSxΔSy12[Sx,Sy]=122=24\Delta S_x \cdot \Delta S_y \geq \frac{1}{2}|\langle [S_x, S_y] \rangle| = \frac{1}{2}\hbar \cdot \frac{\hbar}{2} = \frac{\hbar^2}{4}

We already computed ΔSx=ΔSy=/2\Delta S_x = \Delta S_y = \hbar/2, so ΔSxΔSy=2/4\Delta S_x \cdot \Delta S_y = \hbar^2/4. The bound is saturated. The uncertainty isn’t just bounded from below — it’s as large as the algebra allows.

This also explains the “6=4+26 = 4 + 2” DOF counting from last lecture in a new light. A single qubit on the Bloch sphere has a definite value along one axis, but that forces uncertainty along the other two. You can’t have definite values for all three components simultaneously — the information budget is 2 real numbers (one axis direction), not 6.

Next lecture, we’ll extend the measurement formalism to two qubits — measuring just one qubit of an entangled pair — and discover that the choice of measurement basis for one qubit determines what happens to the other.


Summary

  1. Entanglement means a two-qubit state cannot be written as ψAϕB|\psi\rangle_A \otimes |\phi\rangle_B. Equivalently: the qubits are not independent, and the amplitude table CC is not rank 1.

  2. The determinant test: arrange amplitudes into a 2×22\times 2 matrix. If det(C)=0\det(C) = 0, the state is a product (not entangled). If det(C)0\det(C) \neq 0, the state is entangled. The determinant measures how far the state is from being factorable.

  3. The four Bell states {Φ±,Ψ±}\{|\Phi^\pm\rangle, |\Psi^\pm\rangle\} are maximally entangled and form an orthonormal basis — an alternative to the computational basis for two qubits. The singlet Ψ|\Psi^-\rangle will be central to Bell’s theorem.

  4. Projective measurement uses projectors mm|m\rangle\langle m| to compute probabilities (pm=mΨ2p_m = |\langle m|\Psi\rangle|^2) and post-measurement states (mmΨ/pm|m\rangle\langle m|\Psi\rangle / \sqrt{p_m}). Measuring in a compatible basis gives a definite result; measuring in an incompatible basis gives a random one.

  5. The uncertainty principle for spin-12\frac{1}{2}: an eigenstate of SxS_x, SyS_y, or SzS_z is definite along one axis and maximally uncertain along the other two (50/50 outcomes). This follows from [Sx,Sy]=iSz[S_x, S_y] = i\hbar S_z and the generalized uncertainty relation ΔAΔB12[A,B]\Delta A \cdot \Delta B \geq \frac{1}{2}|\langle[A,B]\rangle|.


Homework

Problem 1: Bell State Verification

(a) Write the amplitude table for each of the four Bell states and verify that det(C)=1/2|\det(C)| = 1/2 for all of them.

(b) Verify orthogonality: compute Φ+Φ\langle\Phi^+|\Phi^-\rangle, Φ+Ψ+\langle\Phi^+|\Psi^+\rangle, and Ψ+Ψ\langle\Psi^+|\Psi^-\rangle.

(c) Show that Φ+|\Phi^+\rangle can be written as: Φ+=12(+++)|\Phi^+\rangle = \frac{1}{\sqrt{2}}(|{+}{+}\rangle + |{-}{-}\rangle), where ++=++|{+}{+}\rangle = |+\rangle \otimes |+\rangle and =|{-}{-}\rangle = |-\rangle \otimes |-\rangle. What does this say about correlations in the X-basis?


Problem 2: Projective Measurement

A qubit is in state Ψ=130+231|\Psi\rangle = \frac{1}{\sqrt{3}}|0\rangle + \sqrt{\frac{2}{3}}|1\rangle.

(a) Measure in the Z-basis. What are the probabilities for each outcome? What is the state after each outcome?

(b) Measure in the X-basis. Construct the projectors ++|+\rangle\langle+| and |-\rangle\langle-|. What are the probabilities? What is the state after each outcome?

(c) Verify that the probabilities sum to 1 and the projectors satisfy +++=I|+\rangle\langle+| + |-\rangle\langle-| = I.



Problem 3: The Uncertainty Principle for Spin

(a) Verify the commutation relation [σx,σy]=2iσz[\sigma_x, \sigma_y] = 2i\sigma_z by explicit matrix multiplication, where:

σx=(0110),σy=(0ii0),σz=(1001)\sigma_x = \begin{pmatrix} 0 & 1 \\ 1 & 0 \end{pmatrix}, \quad \sigma_y = \begin{pmatrix} 0 & -i \\ i & 0 \end{pmatrix}, \quad \sigma_z = \begin{pmatrix} 1 & 0 \\ 0 & -1 \end{pmatrix}

(b) Show that σi2=I\sigma_i^2 = I for each Pauli matrix. Conclude that (Δσi)2=1σi2(\Delta\sigma_i)^2 = 1 - \langle\sigma_i\rangle^2 in any state.

(c) For the state 0|0\rangle: compute σx\langle\sigma_x\rangle and σy\langle\sigma_y\rangle. Use part (b) to find Δσx\Delta\sigma_x and Δσy\Delta\sigma_y. Are they maximal?

(d) Verify the same result by expanding 0|0\rangle in the X-eigenbasis. What are the probabilities for getting +1 and -1?

(e) For the state +|+\rangle: which component is definite? Compute Δσy\Delta\sigma_y and Δσz\Delta\sigma_z. Verify ΔσyΔσzσx\Delta\sigma_y \cdot \Delta\sigma_z \geq |\langle\sigma_x\rangle|.

(f) Can a state have Δσx=Δσy=Δσz=0\Delta\sigma_x = \Delta\sigma_y = \Delta\sigma_z = 0 (definite values for all three components simultaneously)? Explain using the commutation relations.


Looking Ahead

We now have all the ingredients: entangled Bell states, the determinant test, and the projective measurement formalism. Next lecture, we put them together. What happens when Alice measures one qubit of a Bell pair? How does her measurement basis affect what Bob sees? The answers lead directly to EPR, Bell’s theorem, and the deepest question in quantum foundations: are quantum correlations “just” classical correlations in disguise?